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Green synthesis of Fe3O4 nanoparticles with controlled morphology using urease and their application in dye adsorption
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Update time: 2014-06-12
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Scientists of TIPC,CAS described a simple and environmentally friendly method for preparing highly stable dispersions of Fe3O4 nanoparticles with controlled morphologies in the same synthesis system for the first time. During the process, the Fe3O4 nanoparticles are formed using urease as a multifunctional reagent, including catalyst, template and dispersant, due to its enzymatic activity and special enzymatic steric structure. A possible formation mechanism of such Fe3O4 nanoparticles with various morphologies, including nanospheres, nanosheets and nanorods, is proposed. The asprepared nanoparticles show larger specific surface area and stronger magnetism, which make them perform better dye adsorption capacity and have a great potential in application of wastewater treatment. 
Dalton Transactions , 2014
SEM images of Fe3O4 nanospheres (a-b), Fe3O4 nanosheets (c-d) and Fe3O4 nanorods (e-f). 

TEM images of Fe3O4 nanospheres (a-b), Fe3O4 nanosheets (c-d) and Fe3O4 nanorods (e-f).
 
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