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K3MoPO7: the first molybdenum phosphate with edge-sharing MoO6 octahedra and PO4 tetrahedra
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Update time： 2014-06-18
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Scientists of TIPC,CAS report the discovery of a novel molybdenum phosphate K3MoPO7, in which the basic building unit, [P2Mo2O14]6- ring cluster anions, contains the unique edge-sharing MoO6 and PO4 polyhedra. The structural stability of K3MoPO7 is confirmed by both experimental and first-principles studies.
RSC Adv., 2014,
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