Name: ZHANG Liping
E-mail: lpzhang@mail.ipc.ac.cn
Resume:
ZHANG Liping, female, was born in 1964 at Changchun, Jilin province. She graduated from the Chemistry Department of Beijing Normal University in 1987 and entered former Technical Institute of Physics And Chemistry, CAS, in 1990. She obtained the master's degree in physical chemistry in 1993 and a doctorate in organic chemistry in 1996. From 1996 to 1998, she was a a postdoctoral in the Department of Medicine and Pharmacy of Korea Research Institute of Chemical & Technology, mainly engaging in the research and development of new methods and technologies for the photochemical synthesis of cardiovascular and cerebrovascular diseases and anticancer drug intermediates. In 2000, she was invited by Japan Society for the Promotion of Science to be a senior visiting professor at the Faculty of Science, Hiroshima University, Japan. She is currently the head of Technical Institute of Physics And Chemistry, CAS, doctoral supervisor as well as the member of Committee of Academic Affairs, Committee of Academic Degree and Recruitment team of our institute. She has long been engaged in research in organic photochemistry and synthetic photochemistry. These include the study of photochemical and photo-physical behaviors in special micro-reactors, the use of special micro-reactors to improve the selectivity of photochemical reactions, the study of intra-molecular long-range light-induced electron transfer and energy transfer, and new methods and techniques for photochemical synthesis, etc. A series of innovative results have been achieved. She has published more than 60 papers in core journals such as J. Am. Chem. Soc. and J. Phys. Chem., and has received extensive attention from peer experts at home and abroad. She also participated in and completed 4 projects of the National Natural Science Foundation of China, 1 major project of the Ninth Five-Year Plan of CAS, 1 key innovation project of CAS, 1 project of 973, and 1 project of 863.
Research Field:
The laboratory has been engaged in organic photochemistry and photophysical processes for many years, and has carried out systematic research on aspects such as micro-environmental and magnetic field effects in photochemical reactions, hydrophobic and lipophobicity effects, photochemistry and photophysics in molecular aggregates, photochemistry of host-guest compounds, and photoinduced electrons transfer and energy transfer, and many innovative results have been obtained. Key research fields include: (1) remote light-induced electron transfer and energy transfer in supramolecular systems; (2) stereoselective studies of photochemical reactions in nanoreactors; (3) application of new methods and techniques for photochemical synthesis Development research; (4) molecular design and application research of organic light functional materials.
Publications:
1、C.-H. Tung, L.-P. Zhang, Y. Li, H. Cao, Y. Tanimoto, “Benzophenone-Initiated Photoisomerization of the Norbornadiene Group in a Benzophenone- Steroid-Norbornodiene System via Long-Distance Intramolecular Triplet Energy Transfer”, J. Phys. Chem., 1996, 100, 4480.
2、C.-H. Tung, L.-P. Zhang, Y. Li, H. Cao, Y. Tanimoto, “Intramolecular Long-Distance Electron Transfer and Triplet Energy Transfer. Photophysical and Photochemical Studies on a Norbornadiene-Steroid-Benzidine System”, J. Am. Chem. Soc., 1997, 5348
3、Ming Xu, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “Enhancement of Photoinduced Intramolecular Cross-Cycloaddition of a-(9-Anthryl)-w-(1-Naphthoyl) End-labeled Poly(ethylene glycol) via Lipophobic Interactions and Complexation with Metal Cations”, Tetrahedron Letters, 2001, 42, 9249-9252.
4、Xiao-Hong Li, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, Chi-Ming Che, “Luminescence and Photocatalytic Properties of a Platinum(II)-Quaterpyridine Complex Incorporated in Nafion Membrane”, Chemical Communications, 2001, 2280-2281.
5、Da-Yong Wu, Li-Ping Zhang, Li-Zhu Wu, Bo-jie Wang, Chen-Ho Tung, “Water-in-Oil Microemulsions as Microreactors to Control the Regioselectivity in the Photocycloaddition of 9-Substituted Anthracenes” Tetrahedron Lett., 2002, 43(7), 1281-1283.
6、Xiao-Hong Li, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung “Controlled Photocyclization, Photodimerizaiton and Photoisomerization of Stilbazole Salts within Nafion Membranes”. Org. Lett. 2002, 4, 1175-1177.
7、Ming Xu, Xiao-Gang Fu, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “Photocontrollable Ion Transport across a Liquid Membrane by Anthracene End-Labeled Oligo-Oxyethylenes”, Phys. Chem. Chem. Phys. 2002, 4, 4030-4035.
8、Jiu-Yan Li, Ming-Li Peng, Li-Ping Zhang, Li-Zhu Wu, Chen-Ho Tung “Long-lived Photoinduced Charge Separation in Carbazole-Pyrene-Viologen System Incorporated in Langmuir-Blodgett Films of Substituted Diazacrownether”, J. Photochem. Photobio. A: Chem. 2002, 150, 101-108.
9、Qing–Zheng Yang, Li–Zhu Wu, Zi-Xin Wu, Li–Ping Zhang, Chen–Ho Tung, “Long-Lived Emission from Platinum(II) Terpyridyl Acetylide Complexes”, Inorg. Chem., 2002, Vol. 41, 22, 5653-5655.
10、Kai Song, Ming-Li Peng, Ming Xu, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “A Comparative Study on Photosensitized Oxidation of trans-2-Vinylthiophenes with trans-3-Vinylthiophenes”, Tetrahedron Lett., 2002, 43(37), 6633 – 6636.
11、Xin-Jing Tang, Li-Zhu Wu, Li-Ping Zhang and Chen-Ho Tung, “Two-photon-pumped Frequency-Upconverted Lasing and Optical Power Limiting Properties of Vinylbenzothiazole-Containing Compounds in Solution”, Phys. Chem. Chem. Phys. 2002, 4 (23), 5744 – 5747.
12、Chen-Ho Tung, Li-Zhu Wu, Li-Ping Zhang, Bin Chen, “Supramolecular Systems as Microreactors: Control of Product Selectivity in Organic Phototransformation”, Acc. Chem. Res., 2003, Vol.36, 39-47.
13、Li-Ping Zhang, Bin Chen, Li-Zhu Wu, Chen-Ho Tung, Hong Cao, Yoshifumi Tanimoto, “Remote Activation of the Quadricyclane Group in a Quadricyclane-Steroid- {Dibenzoylmethanatoboron Difluoride} System by Intramolecular Electron Transfer”, J. Phys. Chem. A., 2003, 107(18), 3438-3442.
14、Da-Yong Wu, Bin Chen, Xiao-Gang Fu, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “Nanosized Particles of Organically Modified Silica as Microreactors to Enhance the Regioselectivity in the Photocycloaddition of 9-Substituted Anthracenes”, Org. Lett. 2003, 5(7), 1075-1077.
15、Dong Zhang, Li-Zhu Wu, Qing-Zheng Yang, Xiao-Hong Li, Li-Ping Zhang, Chen-Ho Tung “Versatile Photosensitization System for 1O2-Mediated Oxidation of Alkenes Based on Nafion-Supported Platinum (II) Terpyridyl Acetylide Complex”, Org. Lett. 2003, 5(18),3221-3224.
16、Dong Zhang, Li–Zhu Wu, Li Zhou, Xue Han, Qing-Zheng Yang, Li–Ping Zhang, Chen–Ho Tung, “Photocatalytic Hydrogen Production from Hantzsch 1,4-Dihydropyridines by Platinum (II) Terpyridyl Complexes in Homogeneous Solution”, J. Am. Chem. Soc., 2004, 126(11), 3440-3441.
17、You-Wei Wang, Qing–Zheng Yang, Li–Zhu Wu, Li–Ping Zhang and Chen–Ho Tung, “Synthesis and Luminescent Properties of Acetylide-bridged Dinuclear Platinum(II) Terpyridyl Complex”, Chin. J. Chem., 2004, 22(1), 114-116.
18、Qing–Zheng Yang, Li–Zhu Wu, Zi-Xin Wu, Li–Ping Zhang and Chen–Ho Tung, “A Novel Proton-Controlled Molecular Switch with Luminescence and Color Signaling Based on Platinum(II) Terpyridyl Acetylide Complex”, Chin. J. Chem. 2004, 22(1), 1-3.
19、Qing–Zheng Yang, Qing-Xiao Tong, Li–Zhu Wu, Zi-Xin Wu, Li–Ping Zhang and Chen–Ho Tung, “Switch of the Lowest Excited-States of Terpyridylplatinum(II) Acetylide Complexes Bearing Amino or Azacrown Moieties by Proton and Cations”, Eur. J. Inorg. Chem. 2004, 1948-1954.
20、Yue Yang, Dong Zhang, Li-Zhu Wu,* Bin Chen, Li-Ping Zhang, and Chen-Ho Tung*, “Photosensitized Oxidative Deprotection of Oximes to Their Corresponding Carbonyl Compounds by Platinum(II) Terpyridyl Acetylide Complex”, J. Org. Chem. 2004, 69(14).
21、4788-4791. Chun-Chang Zhao, Qing-Xiao Tong, Zhan-Ting Li, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “Inner-assembly singlet energy transfer in naphthalene-anthracence system linked by 2-ureido-4[1H]-pyrimidinone binding module”, Tetrahedron. Lett., 2004, 45(36), 6807-6811.
22、Qing–Zheng Yang, Li–Zhu Wu, He Zhang, Bin Chen, Zi-Xin Wu, Li–Ping Zhang and Chen–Ho Tung, “A Luminescent Chemosensor with Specific Response for Mg2+”, Inorg. Chem., 2004, 43, 5195-5197.
23、Yu-Zhe Chen, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “Confined Space Controlled Hydroperoxidation of Trisubstituted Alkenes Adsorbed on Pentasil Zeolites”, J. Org. Chem. 2005, 70(12), 4676-4681.
24、Hai Xue, Xin-Jing Tang, Li-Zhu Wu, Li-Ping Zhang and Chen-Ho Tung, “Highly Selective Colorimetric and Electrochemical Pb2+ Detection Based on the Intramolecular Charge Transfer Transition of TTF-π-Pyridine Derivatives.” J. Org. Chem. 2005, 70(24), 9727-9734.
25、Yao-Peng Zhao, Chun-Chang Zhao, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, Yuan-Jiang Pan, “First Fluorescent Sensor for Fluoride Based on 2-Ureido-4[1H]-Pyrimidinone Quadruple Hydrogen-bonded AADD Supramolecular Assembly”, J. Org. Chem. 2006, 71, 2143-2146.
26、Li Zhou, Li-Zhu Wu, Li-Ping Zhang, Chen-Ho Tung, “Photochemical Rearomatization and Dearomatization of Tricarbonyl(?5-cyclohexadienyl)manganese Complexes”, Organometallics, 2006, 25, 1707-1711.
27、Xiao-He Xu, Xiao-Gang Fu, Li-Zhu Wu, Bin Chen, Li-Ping Zhang, Chen-Ho Tung, Hai-Feng Ji, Kirk S. Schanze, Rui-Qin Zhang, “Intramolecular Triplet Energy Transfer in Donor-Acceptor Molecules Linked by Crown-Ether Bridge”, Chem. Eur. J. 2006, ASAP.
Projects:
1, General Programs of The National Natural Science Foundation of China—Principal “Study on the Reaction of Photo-oxidation to Form Ruthenium Carbonyl Compounds” (2005-2007)
2, General Programs of The National Natural Science Foundation of China—Principal "Photochemical Reaction of Aromatic Tricarbonyl Manganese Complex and Its Application in Synthetic Chemistry" (2006-2008)
3, Key Project of The National Natural Science Foundation of China—Main Participant "Several basic photochemical problems in photoelectron functional materials" (2004-2007)
4, National Key Basic Research and Development Program 973 Project - Main Participant "Chemical-Organic Functional Microstructures and Assembly of Molecular Aggregates" (2001-2005)
PEOPLE